Graphene: Magnetic sensor 100 times more sensitive than silicon equivalent

 

Scientists have created a graphene-based magnetic sensor 100 times more sensitive than an equivalent device based on silicon. Bosch has long been involved in sensor technology, notably in the automotive sector. In 2008, the company expanded beyond its pressure, acceleration and gyroscopic motion sensors, to geomagnetic, temperature, humidity, air quality and sound pressure devices, including for use in consumer electronics devices such as mobile phones. Interested in whether graphene could enable new applications and improved sensor performance, Bosch has been investigating the use of the two-dimensional material in its pressure, magnetic, humidity, gas and sound pressure devices. The first step was to look at fabrication methods. Top-down approaches to graphene device fabrication such as mechanical and chemical exfoliation would not work on a commercial scale, so Bosch focussed instead on bottom-up techniques such as the thermal decomposition of silicon carbide, and chemical vapour deposition onto metal surfaces. The latter is certainly suited to mass production, and the former possibly so. Roelver cautioned that graphene-based sensor applications will require 5-10 years before they can compete with established technologies. This is due to the current lack of large-scale wafer-based and transfer-free synthesis techniques. Various substrates were considered by the Bosch and Max-Planck researchers, who in the case of their magnetic sensor settled on hexagonal boron nitride. This is for reasons of both cost and technical performance. Bosch's magnetic sensors are based on the Hall effect, in which a magnetic field induces a Lorentz force on moving electric charge carriers, leading to deflection and a measurable Hall voltage. Sensor performance is defined by two parameters: (1) sensitivity, which depends on the number of charge carriers, and (2) power consumption, which varies inversely with charge carrier mobility. It is high carrier mobility that makes graphene useful in such applications, and the results achieved by the Bosch-led team confirm this. Comparing and contrasting materials, Roelver in his Graphene Week presentation showed that the worst case graphene scenarios roughly match a silicon reference. In the best case scenario, the result is a huge improvement over silicon, with much lower source current and power requirements for a given Hall sensitivity. In short, graphene provides for a high-performance magnetic sensor with low power and footprint requirements. In terms of hard numbers, the result shown by Roelver centred on a direct comparison between the sensitivity of a silicon-based Hall sensor with that of the Bosch-MPI graphene device. The silicon sensor has a sensitivity of 70 volts per amp-tesla, whereas with the boron nitride and graphene device the figure is 7,000. That is a two orders of magnitude improvement. After summarising this stunning research result, Roelver concluded on a high note, stressing that Bosch takes graphene very seriously indeed as a future commercial technology. Story Source: The above post is reprinted from materials provided by Graphene Flagship. The original item was written by Francis Sedgemore. Note: Materials may be edited for content and length.

Spiraling laser pulses could change graphene

Thu, 05/28/2015 - 11:46am

SLAC National Accelerator Laboratory

This illustration depicts the structure of graphene, which consists of a single layer of carbon atoms arranged in a honeycomb pattern. A new simulation suggests that spiraling pulses of polarized laser light could change graphene's nature, turning it from a metal to an insulator. Led by researchers at SLAC and Stanford, the study paves the way for experiments that create and control new states of matter with this specialized form of light. Image: AlexanderAlUS via Wikimedia Commons

A new study predicts that researchers could use spiraling pulses of laser light to change the nature of graphene, turning it from a metal into an insulator and giving it other peculiar properties that might be used to encode information.

The results, published in Nature Communications, pave the way for experiments that create and control new states of matter with this specialized form of light, with potential applications in computing and other areas.

“It’s as if we’re taking a piece of clay and turning it into gold, and when the laser pulse goes away the gold goes back to clay,” said Thomas Devereaux, a professor at the U.S. Dept. of Energy (DOE)’s SLAC National Accelerator Laboratory and director of the Stanford Institute for Materials and Energy Sciences (SIMES), a joint SLAC/Stanford institute.

“But in this case,“ he said, “our simulations show that we could theoretically change the electronic properties of the graphene, flipping it back and forth from a metallic state, where electrons flow freely, to an insulating state. In digital terms this is like flipping between zero and one, on and off, yes and no; it can be used to encode information in a computer memory, for instance. What makes this cool and interesting is that you could make electronic switches with light instead of electrons.”

Devereaux led the study with Michael Sentef, who began the work as a postdoctoral researcher at SLAC and is now at the Max Planck Institute for the Structure and Dynamics of Matter in Germany.

Tweaking a wonder material

Graphene is a pure form of carbon just one atom thick, with its atoms arranged in a honeycomb pattern. Celebrated as a wonder material since its discovery 12 years ago, it’s flexible, nearly transparent, a superb conductor of heat and electricity and one of the strongest materials known. But despite many attempts, scientists have not found a way to turn it into a semiconductor—the material at the heart of microelectronics.

An earlier study demonstrated that it might be possible to take a step in that direction by hitting a material with circularly polarized light—light that spirals either clockwise or counterclockwise as it travels, a quality that can also be described as right- or left-handedness. This would create a “band gap,” a range of energies that electrons cannot occupy, which is one of the hallmarks of a semiconductor.

In the SIMES study, theorists used the DOE’s National Energy Research Scientific Computing Center at Lawrence Berkeley National Laboratory to perform large-scale simulations of an experiment in which graphene is hit with circularly polarized pulses a few millionths of a billionth of a second long.

Getting as close to real as possible

“Previous studies were based on analytical calculations and on idealized situations,” said Martin Claassen, a Stanford graduate student in Devereaux’s group who made key contributions to the study. “This one tried to simulate what happens in as close to real experimental conditions as you can get, right down to the shape of the laser pulses. Doing such a simulation can tell you what types of experiments are feasible and identify regions where you might find the most interesting changes in those experiments.”

The simulations show that the handedness of the laser light would interact with a slight handedness in the graphene, which is not entirely uniform. This interaction leads to interesting and unexpected properties, said SLAC staff scientist and study co-author Brian Moritz. Not only does it produce a band gap, but it also induces a quantum state in which the graphene has a so-called “Chern number” of either one or zero, which results from a phenomenon known as Berry curvature and offers another on/off state that scientists might be able to exploit.

Insights go beyond graphene

While this study does not immediately open ways to make electronic devices, it does give researchers fundamental insights that advance the science in that direction. The results are also relevant to materials called dichalcogenides, which are also two-dimensional sheets of atoms arranged in a honeycomb structure.

Dichalcogenides are the focus of intense research at SIMES and around the world because of their potential for creating “valleytronic” devices. In valleytronics, electrons move through a two-dimensional semiconductor as a wave with two energy valleys whose characteristics can be used to encode information. Possible applications include light detectors, low-energy computer logic and data storage chips and quantum computing. In addition to the work on graphene, members of the research team have also been simulating experiments involving the interaction of light with dichalcogenides.

“Ultimately,” Moritz said, “we’re trying to understand how interaction with light can alter a material’s character and properties to create something that’s both new and interesting from a technological point of view.”

Source: SLAC National Accelerator Laboratory

See-through, one-atom-thick, carbon electrodes powerful tool to study brain disorders

 

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Photograph of a 16-electrode transparent array. Inset, a closer view showing the electrode area. Fainted squares are the recording electrodes.

Researchers from the Perelman School of Medicine and School of Engineering at the University of Pennsylvania and The Children's Hospital of Philadelphia have used graphene -- a two-dimensional form of carbon only one atom thick -- to fabricate a new type of microelectrode that solves a major problem for investigators looking to understand the intricate circuitry of the brain.

Pinning down the details of how individual neural circuits operate in epilepsy and other neurological disorders requires real-time observation of their locations, firing patterns, and other factors, using high-resolution optical imaging and electrophysiological recording. But traditional metallic microelectrodes are opaque and block the clinician's view and create shadows that can obscure important details. In the past, researchers could obtain either high-resolution optical images or electrophysiological data, but not both at the same time.

The Center for NeuroEngineering and Therapeutics (CNT), under the leadership of senior author Brian Litt, PhD, has solved this problem with the development of a completely transparent graphene microelectrode that allows for simultaneous optical imaging and electrophysiological recordings of neural circuits. Their work was published this week in Nature Communications.

"There are technologies that can give very high spatial resolution such as calcium imaging; there are technologies that can give high temporal resolution, such as electrophysiology, but there's no single technology that can provide both," says study co-first-author Duygu Kuzum, PhD. Along with co-author Hajime Takano, PhD, and their colleagues, Kuzum notes that the team developed a neuroelectrode technology based on graphene to achieve high spatial and temporal resolution simultaneously.

Aside from the obvious benefits of its transparency, graphene offers other advantages: "It can act as an anti-corrosive for metal surfaces to eliminate all corrosive electrochemical reactions in tissues," Kuzum says. "It's also inherently a low-noise material, which is important in neural recording because we try to get a high signal-to-noise ratio."

While previous efforts have been made to construct transparent electrodes using indium tin oxide, they are expensive and highly brittle, making that substance ill-suited for microelectrode arrays. "Another advantage of graphene is that it's flexible, so we can make very thin, flexible electrodes that can hug the neural tissue," Kuzum notes.

In the study, Litt, Kuzum, and their colleagues performed calcium imaging of hippocampal slices in a rat model with both confocal and two-photon microscopy, while also conducting electrophysiological recordings. On an individual cell level, they were able to observe temporal details of seizures and seizure-like activity with very high resolution. The team also notes that the single-electrode techniques used in the Nature Communications study could be easily adapted to study other larger areas of the brain with more expansive arrays.

The graphene microelectrodes developed could have wider application. "They can be used in any application that we need to record electrical signals, such as cardiac pacemakers or peripheral nervous system stimulators," says Kuzum. Because of graphene's nonmagnetic and anti-corrosive properties, these probes "can also be a very promising technology to increase the longevity of neural implants." Graphene's nonmagnetic characteristics also allow for safe, artifact-free MRI reading, unlike metallic implants.

Kuzum emphasizes that the transparent graphene microelectrode technology was achieved through an interdisciplinary effort of CNT and the departments of Neuroscience, Pediatrics, and Materials Science at Penn and the division of Neurology at CHOP.

Ertugrul Cubukcu's lab at Materials Science and Engineering Department helped with the graphene processing technology used in fabricating flexible transparent neural electrodes, as well as performing optical and materials characterization in collaboration with Euijae Shim and Jason Reed. The simultaneous imaging and recording experiments involving calcium imaging with confocal and two photon microscopy was performed at Douglas Coulter's Lab at CHOP with Hajime Takano. In vivo recording experiments were performed in collaboration with Halvor Juul in Marc Dichter's Lab. Somatasensory stimulation response experiments were done in collaboration with Timothy Lucas's Lab, Julius De Vries, and Andrew Richardson.

As the technology is further developed and used, Kuzum and her colleagues expect to gain greater insight into how the physiology of the brain can go awry. "It can provide information on neural circuits, which wasn't available before, because we didn't have the technology to probe them," she says. That information may include the identification of specific marker waveforms of brain electrical activity that can be mapped spatially and temporally to individual neural circuits. "We can also look at other neurological disorders and try to understand the correlation between different neural circuits using this technique," she says.

The work was supported by grants from the National Institutes of Health (R01-NS063039, 1U24 NS 63930-01A1, R01-NS038572, RO1-NS082046), Citizens United for Research in Epilepsy (CURE) through the Julie's Hope Award, and the Mirowski Family Foundation.